Adjust the playing time in the manual timing bar (if necessary).

Click with the right mouse button on the bullypoint where the faceoff takes place

Click on FACEOFF in the context menu

In the right view, select the player of the home team and the visiting team

Click on "Team" in the action bar to select which team won the faceoff. (The displayed team - in the example RIA has - won).

Press F4 to save (this also happens automatically 1 time per minute).